AP MCQ 07ABCDEFGHIJKLMN PART 2 Question 01: Addition of an inert gas such as neon, to an equilibrium mixture of nitrogen, hydrogen and ammonia (shown below), will result in what change? N2 + 3H2 ⇌ 2NH3 A shift toward the prodcut side since adding neon increases the partial pressure of the reactants A shift toward the prodcut side since adding neon increases the total pressure in the system No change since the partial pressures of reactants and products do not change, and hence Q remains the same No change since neon gas will be evenly distributed amongst the reactant and product side of the reaction Question 02: Which of the following changes will result in more CO(g) being created in the equilibrium mixture? H2(g) + CO2(g) ⇌ H2O(g) + CO(g) The addition of water vapor A decrease in the size of the reaction vessel Introducing a dehydrating reagent to the system Addition of catalyst Question 03: In which of the following equilibrium systems will the mole fraction of products be increased, by the decreasing the total pressure on the system? N2(g) + 3H2(g) ⇌ 2NH3(g) N2O4(g) ⇌ 2NO2(g) 3O2(g) ⇌ 2O3(g) H2(g) + CO2(g) ⇌ H2O(g) + CO(g) Question 04: Dichromate(VI) ions (orange) can be converted to chromate(VI) ions (yellow) by adding water. The equilibrium below can be established. Which of the following is initially UNCHANGED by the addition of hydroxide ions to the equilibrium mixture? Cr2O72-(aq) + H2O(l) ⇌ 2CrO42-(aq) + 2H+(aq) The color of the solution The concentration of H+ ions in solution The concentration of dichromate(VI) ions in solution The oxidation number of the Cr Questions 05-06: In the equilibrium shown below, Fe3+ is a yellow brown color, and the [FeSCN]2+ ion is blood red. Fe3+ + SCN- ⇌ [FeSCN]2+ ∆H = negative Question 05: If a reaction mixture is plunged into an ice-bath, what observation might one reasonably expect to make? The reaction mixture turning a blood red color The formation of SCN- ions The reaction mixture becoming increasingly yellow/brown in color The formation of Fe3+ ions Question 06: Addition of hydroxide ions to the system will result in what, observable change? The formation of a precipitate and no color change The formation of a precipitate and a color change A color change but no precipitate formed No color change and no precipitate formed Question 07: Consider the equilibrium shown below. 3Cl2(g) + 6OH-(aq) ⇌ 5Cl-(aq) + ClO3-(aq) + 3H2O(l) Assuming silver hydroxide to be soluble, addition of which of the following to the equilibrium mixture, will cause the equilibrium to shift to the product side? AgNO3(aq) NaCl(aq) NaClO3(aq) HCl(aq) Question 08: Which of the following equilibrium mixtures is unaffected by a change in the volume of the reaction vessel? CaCO3(s) ⇌ CaO(s) + CO2(g) H2(g) + I2(s) ⇌ 2HI(g) C2H4(g) + H2(g) ⇌ C2H6(g) CO2(g) + H2(g) ⇌ CO(g) + H2O(g) Question 09: Which change in conditions will cause the concentration of products in the equilibrium mixture below, to be increased? N2(g) + 3H2(g) ⇌ 2NH3(g) ΔH = -92 kJ mol-1 Increasing temperature Removing hydrogen from the equilibrium mixture Reducing the volume of the reaction vessel Removing nitrogen from the equilibrium mixture Question 10: Consider the equilibrium system shown below. The equilibrium position can be moved to the product side by applying which of the following changes? CO(g) + 2H2(g) ⇌ CH3OH(g) Adding more methanol (CH3OH(g)) Adding a catalyst Adding more hydrogen Decreasing the pressure (by increasing the volume of the container) Δ