AP MCQ 05ABCDEFGHIJK PART 4 Question 01: Which of the following best describes the action of a catalyst and how a reaction rate is increased when one is present? Concentrations of reactants are increased in the presence of a catalyst Catalysts raise the temperature of a reaction mixture A catlayst increases the activation energy A catalyst provides a reaction pathway with a lower activation energy Question 02: The reaction mechanism below shows the destruction of ozone in the earth's atmosphere. Step 1: Cl(g) + O3(g) → ClO(g) + O2(g) Step 2: ClO(g) + O(g) → Cl(g) + O2(g) Which species is the catalyst, and how can it by identified? O3 since it is produced from O2 Cl since it is present at both the beginning and at the end of the reaction ClO since it is formed in one step and used in a subsequent one O2 since it is a product of the reaction Question 03: Which of the following is not a characteristic of a catalyst? It is the same at the end of a reaction as it is at the beginning It can shift the equilibrium position toward the product side of a reaction It may be homogeneous or heterogeneous It provides a pathway of lower activation energy Question 04: On the diagram shown below, which of the values are affected by the addition of a catalyst? I only I & III only II & III only I, II & III Question 05: What happens when a catalyst is added to an equilibrium mixture? The rate of the forward reaction increases and the rate of the backward reaction decreases The rates of both forward and the backward reactions increase The enthalpy change (∆H) increases A greater % of products appear in the mixture Question 06: A few drops of sulfuric acid are observed to increase the rate of a reaction between a liquid alcohol and a liquid carboxylic acid, whereas a transition metal catalyst does the same in the case of the production of ammonia gas from nitrogen and hydrogen gases. Which statement best describes these observations? The transition metal is a homogeneous catalyst and the acid is a heterogeneous catalyst The transition metal is a heterogeneous catalyst and the acid is a homogeneous catalyst The transition metal and the acid are heterogeneous catalysts The transition metal and the acid are homogeneous catalysts Question 07: Based purely on a set of elementary steps that make up a reaction mechanism, how might one recognize a catalyst? It never changes at all during the whole reaction It is not present at the beginning of the reaction but is present at the end It is present at the beginning of the reaction but not present at the end of the reaction It may change during the reaction, but is the same at the end of the reaction as it was at the beginning Question 08: When enzymes are used to catalyze substrates in biological reactions, the rate of product formation is often found to ultimately plateau. Which explanation would NOT account for this observation? The reaction is now going in reverse The substrate has been used up The reaction has stopped All of the active sites on the enzyme have been filled Question 09: When a reversible reaction is exposed to a catalyst, which statement correctly summarizes the change in the rate of the forward and backward reactions? There is no change in either rate The rate of the backward reaction increases more than the rate of the forward reaction The rate of the forward reaction increases more than the rate of the backward reaction Both rates increase to the same extent Question 10: In the following mechanism, what is the catalyst? A + B → C + D C + A → B + D A B C D Δ